Pyrolysis kinetics of coking coal mixed with biomass under non-isothermal and isothermal conditions.
Identifieur interne : 002083 ( Main/Exploration ); précédent : 002082; suivant : 002084Pyrolysis kinetics of coking coal mixed with biomass under non-isothermal and isothermal conditions.
Auteurs : Ha Myung Jeong [Corée du Sud] ; Myung Won Seo [Corée du Sud] ; Sang Mun Jeong [Corée du Sud] ; Byung Ki Na [Corée du Sud] ; Sang Jun Yoon [Corée du Sud] ; Jae Goo Lee [Corée du Sud] ; Woon Jae Lee [Corée du Sud]Source :
- Bioresource technology [ 1873-2976 ] ; 2014.
Descripteurs français
- KwdFr :
- MESH :
- analyse : Charbon, Coke.
- composition chimique : Liriodendron.
- Biocarburants, Biomasse, Cinétique, Microscopie électronique à balayage, Porosité, Température élevée, Thermogravimétrie.
English descriptors
- KwdEn :
- MESH :
- chemical , analysis : Coal, Coke.
- chemical : Biofuels.
- chemistry : Liriodendron.
- Biomass, Hot Temperature, Kinetics, Microscopy, Electron, Scanning, Porosity, Thermogravimetry.
Abstract
To investigate the kinetic characteristics of coking coal mixed with biomass during pyrolysis, thermogravimetric (TG) and thermo-balance reactor (TBR) analyses were conducted under non-isothermal and isothermal condition. Yellow poplar as a biomass (B) was mixed with weak coking coal (WC) and hard coking coal (HC), respectively. The calculated activation energies of WC/B blends were higher than those of HC/B blends under non-isothermal and isothermal conditions. The coal/biomass blends show increased reactivity and decreased activation energy with increasing biomass blend ratio, regardless of the coking properties of the coal. The different char structures of the WC/B and HC/B blends were analyzed by BET and SEM.
DOI: 10.1016/j.biortech.2014.01.005
PubMed: 24472746
Affiliations:
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Electronic address: smjeong@chungbuk.ac.kr.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>Department of Chemical Engineering, Chungbuk National University, 52 Naesudong-ro, Heungdeok-gu, Cheong ju 361-763</wicri:regionArea><wicri:noRegion>Cheong ju 361-763</wicri:noRegion></affiliation></author><author><name sortKey="Na, Byung Ki" sort="Na, Byung Ki" uniqKey="Na B" first="Byung Ki" last="Na">Byung Ki Na</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemical Engineering, Chungbuk National University, 52 Naesudong-ro, Heungdeok-gu, Cheong ju 361-763, Republic of Korea.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>Department of Chemical Engineering, Chungbuk National University, 52 Naesudong-ro, Heungdeok-gu, Cheong ju 361-763</wicri:regionArea><wicri:noRegion>Cheong ju 361-763</wicri:noRegion></affiliation></author><author><name sortKey="Yoon, Sang Jun" sort="Yoon, Sang Jun" uniqKey="Yoon S" first="Sang Jun" last="Yoon">Sang Jun Yoon</name><affiliation wicri:level="1"><nlm:affiliation>Clean Fuel Laboratory, Korea Institute of Energy Research (KIER), 152 Gajeong-ro, Yuseong-gu, Daejeon 305-343, Republic of Korea.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>Clean Fuel Laboratory, Korea Institute of Energy Research (KIER), 152 Gajeong-ro, Yuseong-gu, Daejeon 305-343</wicri:regionArea><wicri:noRegion>Daejeon 305-343</wicri:noRegion></affiliation></author><author><name sortKey="Lee, Jae Goo" sort="Lee, Jae Goo" uniqKey="Lee J" first="Jae Goo" last="Lee">Jae Goo Lee</name><affiliation wicri:level="1"><nlm:affiliation>Clean Fuel Laboratory, Korea Institute of Energy Research (KIER), 152 Gajeong-ro, Yuseong-gu, Daejeon 305-343, Republic of Korea.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>Clean Fuel Laboratory, Korea Institute of Energy Research (KIER), 152 Gajeong-ro, Yuseong-gu, Daejeon 305-343</wicri:regionArea><wicri:noRegion>Daejeon 305-343</wicri:noRegion></affiliation></author><author><name sortKey="Lee, Woon Jae" sort="Lee, Woon Jae" uniqKey="Lee W" first="Woon Jae" last="Lee">Woon Jae Lee</name><affiliation wicri:level="1"><nlm:affiliation>POSCO Technology Center, POSCO, 6261 Donghaean-ro, Nam-gu, Po hang 790-300, Republic of Korea.</nlm:affiliation><country xml:lang="fr">Corée du Sud</country><wicri:regionArea>POSCO Technology Center, POSCO, 6261 Donghaean-ro, Nam-gu, Po hang 790-300</wicri:regionArea><wicri:noRegion>Po hang 790-300</wicri:noRegion></affiliation></author></analytic><series><title level="j">Bioresource technology</title><idno type="eISSN">1873-2976</idno><imprint><date when="2014" type="published">2014</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Biofuels (MeSH)</term><term>Biomass (MeSH)</term><term>Coal (analysis)</term><term>Coke (analysis)</term><term>Hot Temperature (MeSH)</term><term>Kinetics (MeSH)</term><term>Liriodendron (chemistry)</term><term>Microscopy, Electron, Scanning (MeSH)</term><term>Porosity (MeSH)</term><term>Thermogravimetry (MeSH)</term></keywords><keywords scheme="KwdFr" xml:lang="fr"><term>Biocarburants (MeSH)</term><term>Biomasse (MeSH)</term><term>Charbon (analyse)</term><term>Cinétique (MeSH)</term><term>Coke (analyse)</term><term>Liriodendron (composition chimique)</term><term>Microscopie électronique à balayage (MeSH)</term><term>Porosité (MeSH)</term><term>Température élevée (MeSH)</term><term>Thermogravimétrie (MeSH)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="analysis" xml:lang="en"><term>Coal</term><term>Coke</term></keywords><keywords scheme="MESH" type="chemical" xml:lang="en"><term>Biofuels</term></keywords><keywords scheme="MESH" qualifier="analyse" xml:lang="fr"><term>Charbon</term><term>Coke</term></keywords><keywords scheme="MESH" qualifier="chemistry" xml:lang="en"><term>Liriodendron</term></keywords><keywords scheme="MESH" qualifier="composition chimique" xml:lang="fr"><term>Liriodendron</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Biomass</term><term>Hot Temperature</term><term>Kinetics</term><term>Microscopy, Electron, Scanning</term><term>Porosity</term><term>Thermogravimetry</term></keywords><keywords scheme="MESH" xml:lang="fr"><term>Biocarburants</term><term>Biomasse</term><term>Cinétique</term><term>Microscopie électronique à balayage</term><term>Porosité</term><term>Température élevée</term><term>Thermogravimétrie</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">To investigate the kinetic characteristics of coking coal mixed with biomass during pyrolysis, thermogravimetric (TG) and thermo-balance reactor (TBR) analyses were conducted under non-isothermal and isothermal condition. Yellow poplar as a biomass (B) was mixed with weak coking coal (WC) and hard coking coal (HC), respectively. The calculated activation energies of WC/B blends were higher than those of HC/B blends under non-isothermal and isothermal conditions. The coal/biomass blends show increased reactivity and decreased activation energy with increasing biomass blend ratio, regardless of the coking properties of the coal. The different char structures of the WC/B and HC/B blends were analyzed by BET and SEM. </div></front></TEI><pubmed><MedlineCitation Status="MEDLINE" Owner="NLM"><PMID Version="1">24472746</PMID><DateCompleted><Year>2014</Year><Month>12</Month><Day>10</Day></DateCompleted><DateRevised><Year>2014</Year><Month>04</Month><Day>21</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1873-2976</ISSN><JournalIssue CitedMedium="Internet"><Volume>155</Volume><PubDate><Year>2014</Year><Month>Mar</Month></PubDate></JournalIssue><Title>Bioresource technology</Title><ISOAbbreviation>Bioresour Technol</ISOAbbreviation></Journal><ArticleTitle>Pyrolysis kinetics of coking coal mixed with biomass under non-isothermal and isothermal conditions.</ArticleTitle><Pagination><MedlinePgn>442-5</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1016/j.biortech.2014.01.005</ELocationID><ELocationID EIdType="pii" ValidYN="Y">S0960-8524(14)00012-1</ELocationID><Abstract><AbstractText>To investigate the kinetic characteristics of coking coal mixed with biomass during pyrolysis, thermogravimetric (TG) and thermo-balance reactor (TBR) analyses were conducted under non-isothermal and isothermal condition. Yellow poplar as a biomass (B) was mixed with weak coking coal (WC) and hard coking coal (HC), respectively. The calculated activation energies of WC/B blends were higher than those of HC/B blends under non-isothermal and isothermal conditions. The coal/biomass blends show increased reactivity and decreased activation energy with increasing biomass blend ratio, regardless of the coking properties of the coal. The different char structures of the WC/B and HC/B blends were analyzed by BET and SEM. </AbstractText><CopyrightInformation>Copyright © 2014 Elsevier Ltd. All rights reserved.</CopyrightInformation></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Jeong</LastName><ForeName>Ha Myung</ForeName><Initials>HM</Initials><AffiliationInfo><Affiliation>Department of Chemical Engineering, Chungbuk National University, 52 Naesudong-ro, Heungdeok-gu, Cheong ju 361-763, Republic of Korea.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Seo</LastName><ForeName>Myung Won</ForeName><Initials>MW</Initials><AffiliationInfo><Affiliation>Clean Fuel Laboratory, Korea Institute of Energy Research (KIER), 152 Gajeong-ro, Yuseong-gu, Daejeon 305-343, Republic of Korea.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Jeong</LastName><ForeName>Sang Mun</ForeName><Initials>SM</Initials><AffiliationInfo><Affiliation>Department of Chemical Engineering, Chungbuk National University, 52 Naesudong-ro, Heungdeok-gu, Cheong ju 361-763, Republic of Korea. Electronic address: smjeong@chungbuk.ac.kr.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Na</LastName><ForeName>Byung Ki</ForeName><Initials>BK</Initials><AffiliationInfo><Affiliation>Department of Chemical Engineering, Chungbuk National University, 52 Naesudong-ro, Heungdeok-gu, Cheong ju 361-763, Republic of Korea.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Yoon</LastName><ForeName>Sang Jun</ForeName><Initials>SJ</Initials><AffiliationInfo><Affiliation>Clean Fuel Laboratory, Korea Institute of Energy Research (KIER), 152 Gajeong-ro, Yuseong-gu, Daejeon 305-343, Republic of Korea.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Lee</LastName><ForeName>Jae Goo</ForeName><Initials>JG</Initials><AffiliationInfo><Affiliation>Clean Fuel Laboratory, Korea Institute of Energy Research (KIER), 152 Gajeong-ro, Yuseong-gu, Daejeon 305-343, Republic of Korea.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Lee</LastName><ForeName>Woon Jae</ForeName><Initials>WJ</Initials><AffiliationInfo><Affiliation>POSCO Technology Center, POSCO, 6261 Donghaean-ro, Nam-gu, Po hang 790-300, Republic of Korea.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType><PublicationType UI="D013485">Research Support, Non-U.S. Gov't</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2014</Year><Month>01</Month><Day>10</Day></ArticleDate></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Bioresour Technol</MedlineTA><NlmUniqueID>9889523</NlmUniqueID><ISSNLinking>0960-8524</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D056804">Biofuels</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D003031">Coal</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D003077">Coke</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName UI="D056804" MajorTopicYN="Y">Biofuels</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D018533" MajorTopicYN="N">Biomass</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D003031" MajorTopicYN="N">Coal</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="Y">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D003077" MajorTopicYN="N">Coke</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="Y">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D006358" MajorTopicYN="Y">Hot Temperature</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D007700" MajorTopicYN="N">Kinetics</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D031567" MajorTopicYN="N">Liriodendron</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D008855" MajorTopicYN="N">Microscopy, Electron, Scanning</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D016062" MajorTopicYN="N">Porosity</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D013818" MajorTopicYN="N">Thermogravimetry</DescriptorName></MeshHeading></MeshHeadingList><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">Biomass</Keyword><Keyword MajorTopicYN="N">Co-pyrolysis</Keyword><Keyword MajorTopicYN="N">Hard-coking coal</Keyword><Keyword MajorTopicYN="N">Kinetics</Keyword><Keyword MajorTopicYN="N">Weak-coking coal</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2013</Year><Month>11</Month><Day>11</Day></PubMedPubDate><PubMedPubDate PubStatus="revised"><Year>2013</Year><Month>12</Month><Day>30</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2014</Year><Month>01</Month><Day>03</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2014</Year><Month>1</Month><Day>30</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2014</Year><Month>1</Month><Day>30</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2014</Year><Month>12</Month><Day>15</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">24472746</ArticleId><ArticleId IdType="pii">S0960-8524(14)00012-1</ArticleId><ArticleId IdType="doi">10.1016/j.biortech.2014.01.005</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>Corée du Sud</li></country></list><tree><country name="Corée du Sud"><noRegion><name sortKey="Jeong, Ha Myung" sort="Jeong, Ha Myung" uniqKey="Jeong H" first="Ha Myung" last="Jeong">Ha Myung Jeong</name></noRegion><name sortKey="Jeong, Sang Mun" sort="Jeong, Sang Mun" uniqKey="Jeong S" first="Sang Mun" last="Jeong">Sang Mun Jeong</name><name sortKey="Lee, Jae Goo" sort="Lee, Jae Goo" uniqKey="Lee J" first="Jae Goo" last="Lee">Jae Goo Lee</name><name sortKey="Lee, Woon Jae" sort="Lee, Woon Jae" uniqKey="Lee W" first="Woon Jae" last="Lee">Woon Jae Lee</name><name sortKey="Na, Byung Ki" sort="Na, Byung Ki" uniqKey="Na B" first="Byung Ki" last="Na">Byung Ki Na</name><name sortKey="Seo, Myung Won" sort="Seo, Myung Won" uniqKey="Seo M" first="Myung Won" last="Seo">Myung Won Seo</name><name sortKey="Yoon, Sang Jun" sort="Yoon, Sang Jun" uniqKey="Yoon S" first="Sang Jun" last="Yoon">Sang Jun Yoon</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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